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- Reverend H.R. Ngcayiya – President Ethiopian Church and he was elected Deputy Chaplain
- Sam Makgatho – Vice President
- Alfred Mangena – Conference organiser, later Vice President
- Thomas Mapikela – Speaker
- George Montsioa – Conference organiser, and Recording Secretary
- Richard Msimang - Conference organiser and founding member
- Reverend Mqoboli - Wesleyan Church and he became chief Chaplain
- Thomas Levi Mvabaza - delivered one of the speeches on the programme)
- Meshack Pelem – Vice President
- Solomon Plaatje – Secretary
- Reverend Walter Rubusana – Vice President
- Richard Victor Selope Thema - took over as secretary while Plaatjie was in UK
- Pixley ka Isaka Seme - Conference organiser, convener and gave a keynote address
- Thomas Zini - Migrant Worker who represented the Cape Peninsula Native Association at the founding conference)
Important delegates who could not attend the conference
- John Dube – elected President in absentia
- John Tengo Jabavu
Paramount Chiefs who were appointed Honorary Presidents
- Chief Dalidyebo of the Thembu
- Chief Dinizulu of Zululand
- Chief Khama of Bechuanaland
- Chief Letsie 11 of Basotholand
- Chief Lewanika of Barotseland
- Chief Marclane of Pondoland
- Chief Montsioa of the Barolong
- Chief Mopei Bakgatla